The associating behaviour of the binary mixture of ethylene glycol and acetic acid over the entire concentration range at 25 °C has been investigated through the measured values of dielectric constants. The static dielectric constant 0, high frequency limiting dielectric constant, excess dielectric parameters, the effective Kirkwood correlation factor geff and corrective correlation factor gf for the above binary mixture were determined to obtain the qualitative and quantitative information about the complex formation.

Keywords: Dielectric Constant; Kirkwood Correlation Factor; Multimers;